正高级专业技术岗位
曹大伟
性别:
职务:
职称:研究员
邮编:
传真:
电邮:caodw@isl.ac.cn
地址:青海省西宁市新宁路18号
简历
 

曹大伟,男,博士,研究员,博士生导师。2013年毕业于河西学院化学系,2016年在新疆大学获硕士学位, 2019年在兰州大学获得博士学位。2019-2022年在兰州大学和加拿大麦吉尔大学进行博士后研究,2022年底加入云顶集团游戏登录网站青海盐湖研究所。主要从事光或金属催化的绿色有机化学及盐湖战略资源的综合利用研究,先后主持和参与国家、省部级及横向项目10余项,研究成果在 Nat. Commun., Angew. Chem. Int. Ed.; JACS Au; ACS Catal.; Green Chem.; iScience; Org. Lett.; Chem Commun.; 等期刊发表SCI论文20余篇。


研究领域

光或金属催化的绿色有机化学、盐湖战略资源的综合利用。


获奖及荣誉

第一届国际有机化学会,“Best Researcher Award”(2023年)

甘肃省化工学会,青年学术论坛“优秀学术报告奖”(2019年)


代表论著

[1] Cao D.; Ataya, M.; Chen, Z.; Zeng, H.; Peng, Y.; Khaliullin, R. Z.*; Li, C-J.*. Light-Driven Transition-Metal-Free Direct Decarbonylation of Unstrained Diaryl Ketones via a Dual C‒C Bond Cleavage. Nature Communications, 2022, 13, 1805.

[2] Xia, S.‡; Cao D.‡; Zeng, H.; He, L.-N.*; Li, C-J.*. Nickel-Catalyzed Stereoselective Deoxyalkenylation of Ketones Medi-ated by Hydrazine. JACS Au2022, 2, 1929–1934 (contributed equally).

[3] Cao D.; Li, C.-C.; Zeng, H.; Peng, Y.; Li, C-J.*. C(sp 3 )−C(sp 3 ) bond formation via nickelcatalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine. Nature Communications, 2021, 12, 3729.

[4] Cao D.; Pan, P.; Li, C-J.; Zeng, H.*. Photo-induced transition-metal and photosensitizer free cross–coupling of aryl halides with disulfides. Green Synthesis and Catalysis, 2021, 2, 303–306.

[5] Cao D.; Xia, S.; Pan, P.; Zeng, H.*; Li, C-J.* and Yong Peng*. Light-driven MPV-type reduction of aryl ketones/aldehydes to alcohols with isopropanol under mild conditions. Green Chemistry, 2021, 23, 7539-7543.

[6] Wang, B.‡; Cao D.‡, Ma, X.; Feng, Y.; Zhang, L.; Zhang, Y.*; Liu, C.*. Synthesis of N-arylacetamides via amination of aryltriazenes with acetonitrile under metal-free and mild conditions. Arabian Journal of Chemistry, 2021, 14, 103158. (contributed equally)

[7] Zhang, Y.*. Cao D.; Ma, X.; Tang, C.; Wang, B.; Jin, W.; Xia, Y.; Liu C.*. Ionic-Liquids-Promoted Synthesis of Aryldiazo Sulfones from Aryltriazenes and Sodium Sulfinates under Metal-Free and Ambient Conditions. ChemistrySelect, 2021, 6, 5701-5704.

[8] Cao D.; Chen, Z.; Lv, L.; Zeng, H.; Peng, Y.; Li, C-J.*. Light-Driven Metal-Free Direct Deoxygenation of Alcohols under Mild Conditions. iScience, 2020, 23, 101419.

[9] Cao D.; Yu, J.; Zeng, H.*; Li, C-J.*. Dearomatization-Rearomatization Strategy for Synthesizing Carbazoles with 2,2’-Biphenols and Ammonia by Dual C(Ar)-OH Bond Cleavages. Journal of Agricultural and Food Chemistry, 2020, 68, 13200–13205.

[10] Cao D.; Pan, P.; Zeng, H.*; Li, C-J.*. Umpolung cross-coupling of polyfluoroarenes with hydrazones via activation of C–F bonds. Chemical Communications, 2019, 55, 9323-9326.

[11] Cao D.; Yan, C.; Zhou, P.; Zeng, H.*; Li, C-J.*. Hydrogen Bonding Promoted Simple and Clean Photo-Induced Reduction of C–X Bond with Isopropanol. Chemical Communications, 2019, 55, 767–770.

[12] Zeng, H.*; Cao D.; Qiu, Z.; Li, C-J.*. Palladium-Catalyzed Formal Cross-Coupling of Diaryl Ethers with Amines: Slicing the 4-O-5 Linkage in Lignin Models. Angewandte Chemie International Edition, 2018, 57, 3752–3757.

[13] Cao D.; Zeng, H.*; Li, C-J.*. Formal Cross-Coupling of Diaryl Ethers with Ammonia by Dual C(Ar)-O Bond Cleavage. ACS Catalysis. 2018, 8, 8873–8878.

[14] Cao D.; Zhang, Y.*; Liu, C.*.; Sun, Y.; Abdukader, A.; Wang, B.; Hu, H.; Liu, Q. Ionic Liquid Promoted Diazenylation of N-heterocyclic Derivatives with Aryltriazenes under Mild Conditions. Organic Letters, 2016, 18, 2000-2003. 


承担科研项目情况

引进高层次骨干人才启动经费,基于盐湖资源分离的新型有机萃取剂的合成及其应用,2022-2025,主持