轻合金与吸附分离课题组

发布时间:2023-06-05

  一、课题组名称:轻合金与吸附分离课题组 

  二、课题组简介

  轻合金与吸附分离课题组聚焦盐湖资源绿色高值利用中的关键科学与技术问题开展研究。围绕盐湖高值化利用,开展以盐湖初级化学品为主要原料的镁、锂轻金属及合金制备工艺及装备开发;围绕盐湖资源高效分离和综合利用,以盐湖稀散元素为研究对象,开展以吸附为技术核心的分离材料与工艺开发。 

  研究团队有固定人员18人,其中研究员4人,副研究员4人,高级实验师1人,博士8人,具有出国进修经历4人。另有外聘柔性合作研究员6人,在读博士研究生8人,在读硕士研究生5人,临时聘用技术人员10人。 

  研究方向一:熔盐电解制备镁、锂金属及中间合金新工艺、电解机理研究与工程技术开发 

 

  盐湖氯化镁、氯化锂等为原料,采用熔盐电解法制备镁、锂金属及相关中间合金,研发熔盐电解新工艺,研究电解行为与过程机理,设计制备新型电解槽,开发包括电源系统、电解槽系统、尾气处理系统和自动监测系统在内的整套设备和工程技术。 

  研究方向二:吸附剂设计制备、吸附机理研究及吸附分离工艺开发

 

  针对盐湖中锂、铷、铯、硼、碘等的分离提取或去除,设计制备特效复合和电活性吸附剂,系统研究吸附剂的功能结构、吸附/脱附性能、循环使用性能等,从静电作用、疏水作用、氢键作用、沉淀作用、络合作用等方面深入研究吸附机理,针对特定应用场景开发吸附分离工艺。 

  三、课题组组长 

    吴志坚,男,1965年生于吉林省榆树市。现任云顶集团游戏登录网站青海盐湖研究所研究员,博士生导师,轻合金与吸附分离课题组组长,研究所所长。19831987年在成都科技大学获得学士学位,19871990年在中科院青海盐湖研究所获得硕士学位,19911994年在中科院长春应用化学研究所获得博士学位。19941997年在青岛海洋大学从事博士后研究,20022004年在韩国延世大学从事博士后研究。20153-5月,在美国犹他大学访学研究。目前主要研究领域为盐湖高值化镁、锂产品开发,以及吸附剂的设计制备与分离应用。以盐湖化工副产的氯化镁和稀土产业剩余的成分为原料,采用含水氯化物一步电解制备镁-稀土中间合金,开发了包括电源系统、电解槽系统、尾气处理系统和自动监测系统在内的整套设备和工程技术。以氯化锂和氯化锶为主要原料,采用新工艺和新型电解槽熔盐电解制备了金属锂、铝-锂和铝-锶中间合金,开发了整套工程技术。针对盐湖中锂、铷、铯、硼、碘的分离提取或去除,设计制备了一系列特效复合吸附剂,系统研究了吸附剂的性能,从静电作用、疏水作用、氢键作用、沉淀作用、络合作用等方面深入研究了吸附机理,有针对性地进行了分离提取工艺研究。发表研究论文180余篇,取得授权专利30余件。2008年获得第五届“柳大纲优秀青年科技奖”,2012年中科院人才计划终期考核被评为优秀,2013年享受国务院政府特殊津贴。 

  学术兼职:中国无机盐工业协会锂盐行业分会会长、《盐湖研究》副主编 

  电话(Tel):0971-6307871 

  邮编(P.C.):810008 

  邮箱(Mail):zjwu@isl.ac.cn 

  地址(Add):青海省西宁市新宁路18 

  四、课题组副组长:叶秀深,男,1981年生于山东省临清市。现任云顶集团游戏登录网站青海盐湖研究所研究员,博士生导师,甘河中试基地主任。19992003年在聊城大学化学化工学院获得学士学位。2009年在云顶集团游戏登录网站青海盐湖研究所获得博士学位。20162017年在韩国延世大学访学研究。目前主要研究领域为轻金属及合金熔盐电解制备工艺及装备研发,铷、铯高效吸附材料与工艺研究。发表研究论文80余篇,申请专利40余件。青海省自然科学与工程技术学科带头人,青海省中青年人才托举工程入选者。 

  学术兼职:中国有色金属学会冶金物理化学专家委员会委员,中国化工学会无机酸碱盐专家委员会委员,《无机盐工业》青年编委,《盐湖研究》青年编委会副主任委员。 

  电话(Tel):13897451190 

  邮编(P.C.):810008 

  邮箱(Mail):yexs@isl.ac.cn 

  地址(Add):青海省西宁市新宁路18 

  课题组副组长:刘忠,男,19814月生,博士,研究员,博士生导师。20077月毕业于中国地质大学(武汉),获材料科学与工程学士、岩石矿物材料学硕士学位;20127月毕业于云顶集团游戏登录网站山西煤炭化学研究所,获材料学博士学位;2014-201520182次赴英国圣安德鲁斯大学访问学习。毕业后一直在云顶集团游戏登录网站青海盐湖研究所开展离子吸附分离相关研究,历任研究实习员(2007.07-2012.06),助理研究员(2012.07-2016.06),副研究员(2016.06-2021.09),研究员(2021.10-至今)。研究领域:(1)吸附表面与界面化学:围绕盐湖资源吸附分离,开展液固界面化学中吸附材料的晶体离子输运、表面结构优化、界面结构调控、分离器件组装等相关研究。(2)吸附分离科学与技术:吸附塔优化及吸附工艺过程强化,探索电场辅助离子脱吸附,实现阴阳离子同步高效分离,并结合传统吸附工艺,对盐湖中的锂、铯、溴、硼等资源提取进行技术开发,实现盐湖离子吸附工艺全流程集成研发。发SCI论文30篇,授权专利证书10份,入选青海省培育拔尖人才项目,青海省自然科学与工程学科带头人,2016年入选云顶集团游戏登录网站青年创新促进会,2015年入选中科院人才计划项目,终期评估优秀。 

  电话(Tel):15297182595 

  邮编(P.C.):810008 

  邮箱(Mail):liuzhong@isl.ac.cn 

  地址(Add):青海省西宁市新宁路18 

  五、课题组成员  

  职工:叶秀深、刘海宁、刘忠、李权、钱志强、李明珍、张慧芳、卫文飞、聂国亮、董明哲、罗清龙、张思远、乔英钧、李可昕、王春燕、张效贤、李凯明

 

 

  研究生:房得珍、赵炳、王艳萍、张琼元、马亮、路淼、詹鸿龙、宋忠梅、陈颖、田晨曦、李清泓 

  六、课题组人才专员:张效贤 

  电话(Tel):15261812683 

  邮编(P.C.):810008 

  邮箱(Mail):zhangxiaoxian@isl.ac.cn 

  地址(Add):青海省西宁市新宁路18 

  七、招聘信息

  研究方向1:轻金属及合金材料

  专业要求:无机化学、冶金物理化学、材料学、材料物理与化学、化学工艺、化学工程、材料科学与工程

  学位要求:博士

  拟招人数:2人

  研究方向2:分离材料与技术

  专业要求:无机化学,材料化学,物理化学,化学工艺,材料与化工等相关专业

  学位要求:博士

  招聘人数:3人

  八、招生信息 

  本课题组现有中青年研究生导师9名,面向全国公开招考硕士研究生、博士研究生。博士招生专业包括无机化学、物理化学及材料与化工,硕士招生专业包括无机化学、物理化学、化学工艺及材料与化工。课题组同时依托所化学学科博士后流动站面向全国招收博士后研究人员。 

  欢迎各位青年人才加入“轻合金与吸附分离课题组”! 

  九、科研项目  

  [1] 云顶集团游戏登录网站稳定支持基础研究领域青年团队计划-盐湖关键战略资源的绿色高效分离项目,YSBR-0392022.07-2027.07 

  [2] 镁稀土合金的绿色制备及应用开发,国家科技支撑计划课题,2012BAE01B042012.01-2014.12.  

  [3] 以水合氯化物为原料熔盐电解制备镁-稀土中间合金的科学基础与工程化,国家自然科学基金联合基金重点项目,U21A203232022.01-2025.12. 

  [4] 钾肥生产中浮选药剂的迁移分布规律、耦合回收、去除技术及机理,国家自然科学基金联合基金重点项目,U20A201502021.01-2024.12. 

  [5] 复合分子印迹铷、铯吸附剂的制备及其对柴达木盆地油田水中铷、铯的吸附性能研究,国家自然科学基金面上项目,509721512010.01-2012.12. 

  [6] 生物质三维网络碳气凝胶吸附剂对硼酸根及碘离子高选择性吸附及作用机制研究,国家自然科学基金联合基金培育项目,U15071042016.01-2018.12.  

  [7] 熔盐电解法制备含镁、锶、锂中间合金新技术基础研究,国家自然科学基金联合基金重点项目-课题,U20A201472021.01-2024.12. 

  [8] 盐湖高纯氯化锂的制备及电解氢氧化锂与金属锂的关键科学基础,国家自然科学基金联合基金重点项目-课题,U21A203052021.01-2024.12. 

  [9] 以含水氯化物为原料电解制备镁稀土合金工程技术研究与合金应用,中科院西部行动项目,KZCX2-XB3-062011.01-2013.12. 

  [10] 盐湖卤水吸附法提锂吸附性能优化及锂硼高效分离研究,国家自然科学基金--区域创新发展联合基金(重点支持项目),U20A201412021.01-2024.12 

  [11] 稳定铷铯离子磁性吸附剂的构建及表面力学研究,国家自然科学基金--柴达木盐湖化工科学研究联合基金(培育项目) U16071052017.01-2019.12  

  [12] 磁性铁氧化物晶面调控对铯离子吸附剂嫁接性能的影响研究,国家自然科学基金青年项目,513022802014.01-2016.12 

  [13] 铝锶中间合金的熔盐电解制备及高性能铝锶合金研发,青海省企业研究转化与产业化专项,2017-GX-C22017.01-2019.12. 

  [14] -锌系中间合金制备新技术及其应用合金开发,青海省重点研发与转化计划,2014-GX-216A2014.07-2017.06 

  [15] 年产千吨级金属锂关键技术研发与示范,青海省重点研发与转化计划,2018-GX-1212018.07-2020.12. 

  [16] 盐湖铷、铯高效富集及分离提取的关键科学基础与技术,青海省杰青青年基金项目,2023-ZJ-940J2023.01-2025.12. 

  [17] 盐湖锂吸附剂的制备及分级电场辅助脱附工艺开发,青海省科技成果转化专项,2018-GX-1012018.01-2021.12 

  [18] 锰系锂离子筛结构调控及抗溶损性研究,青海省国际合作专项,2019-HZ-8082019.01-2021.12 

  [19] 盐湖氯化镁电解制备镁系中间合金及电解氯气的高值化利用工程化示范,青海盐湖工业股份有限公司重点科技项目,2021.07-2024.06. 

  [20] 盐湖稀有碱金属吸附剂设计制备和高效分离技术研究,2020青海省基础研究计划,自然科学基金,创新团队,2020-ZJ-901.2020.01-2022.12   

  十、代表性科研成果 

  1.论文及论著 

  (1)Zhao, B., Qiao, Y., Qian, Z., Wei, W., Li, J., Wu, Z., Liu, Z., Unraveling the Li+ desorption behavior and mechanism of Li4Ti5O12 with different facets to enhance lithium extraction. Journal of Materials Chemistry A, 2023, 11, 7094-7104. 

  (2)Zhan, H., Qiao, Y., Qian, Z., Li, J., Wu, Z., Liu, Z., Electrochemical behaviors of porous spherical spinel H1.6Mn1.6O4 with high Li+ adsorption capacity [J]. Separation and Purification Technology. 2023;305(October 2022):122485. 

  (3)Wang, Y., Li, K., Ma, L., Fang, D., Lu, M., Ye, X., Liu, H., Zhang, H., Tan, X., Wu, Z., A magnetic adsorbent with metal-organic framework based on ammonium phosphomolybdenum heteropoly tungstate (AWP): selective adsorption of symbolscript and symbolscript from aqueous resources and stripping with ammonium salts. Hydrometallurgy. 2023, 216, 106011. 

  (4)Zhao, B., Qian, Z., Qiao, Y., Li, J., Wu, Z., Liu, Z., The Li(H2O)n dehydration behavior influences the Li+ ion adsorption on H4Ti5O12 with different facets exposed[J]. Chemical Engineering Journal, 2023, 451: 138870-138882. 

  (5)Zhan, H., Qiao, Y., Qian, Z., Li, J., Wu, Z., Hao, X., Liu, Z., Manganese-based spinel adsorbents for lithium recovery from aqueous solutions by electrochemical technique[J]. Journal of Industrial and Engineering Chemistry, 2022, 114:142-150. 

  (6)Qian, Y., Ding, D., Li, K., Fang, D., Wang, Y., Hu, Y., Ye, X., Liu, H., Wu, Z., Li, J., Extraction of rubidium and cesium from a leach solution of lepidolite with biomass carbon adsorbents. Hydrometallurgy. 2022, 208(12), 150802. 

  (7)Qian, Z., Liu, Z., Wang, S., Ye, X., Wu, Z., Preparation and anti-corrosion properties of SiO2@MWCNTs@PFOTES superhydrophobic coatings on magnesium alloy. International Journal of Electrochemical Science. 2022, 17(1), 220129. 

  (8)Wang, Y., Li, K., Fang, D., Ye, X., Liu, H., Tan, X., Li, Q., Li, J., Wu, Z., Ammonium molybdophosphate/metal-organic framework composite as an effective adsorbent for capture of Rb+ and Cs+ from aqueous solution. Journal of Solid State Chemistry. 2022, 306, 122767. 

  (9)Bai, C., Li, K., Fang, D., Ye, X., Zhang, H., Li, Q., Li, J., Liu, H., Wu, Z., Efficient separation of boron from salt lake brine using a novel flotation agent synthesized from NMDG and 1-bromooctadecane. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2021, 627,127178. 

  (10)Fang, D., Wang, Y., Liu, H., Zhang, H., Ye, X., Li, Q., Li, J., Wu, Z., Efficient extraction of Rb+ and Cs+ by a precipitation flotation process with ammonium phosphowolframate as precipitant. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2021, 608,125581. 

  (11)Qian, Z., Liu, Z., Wang, S., Ye, X., Wu, Z., A durable PVDF/PFOTES-SiO2 superhydrophobic coating on AZ31B Mg alloy with enhanced abrasion resistance performance and anti-corrosion properties. Applied Sciences-Basel. 2021, 11(23), 11172. 

  (12)Qian, F., Zhao, B., Guo M., Wu, Z., Zhou, W., Liu, Z., Surface trace doping of Na enhancing structure stability and adsorption properties of Li1.6Mn1.6O4 for Li+ recovery . Separation and Purification Technology, 2021, 256, 117583-117593.  

  (13)Zhao, B., Qian, F., Guo M., Wu, Z., Liu, Z., The performance and mechanism of recovering lithium on H4Ti5O12 adsorbents influenced by (110) and (111) facets exposed . Chemical Engineering Journal, 2021, 414,128729. 

  (14)Qian, F., Guo M., Qian, Z., Zhao, B., Li, J., Wu, Z., Liu, Z., Enabling highly structure stability and adsorption performances of Li1.6Mn1.6O4 by Al-gradient surface doping. Separation and Purification Technology, 2021, 264, 118433-118443. 

  (15)Li, K., Ding, D., Fang, D., Wang, Y., Ye, X., Liu, H., Tan, X., Li, Q., Wu, Z., Hydrothermal deposition of titanate on biomass carbonaceous aerogel to prepare novel biomass adsorbents for Rb+ and Cs+. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2020, 590,124501. 

  (16)Wang, S., Ye, X., Zhang, H., Qian, Z., Li, Q., Wu, Z., Li, S., Superhydrophobic silane/fluorinated attapulgite@SiO2 composite coatings on magnesium alloy for corrosion protection. Chemistryselect. 2020, 5(33), 10329-10338. 

  (17)Wang, S., Zhang, H., Qian, Z., Ye, X., Wu, Z., Li, S., A facile strategy for preparing superhydrophobic coating on AZ31 magnesium alloy with stable anticorrosion performance. International Journal of Electrochemical Science. 2020, 15(9), 8397-8407. 

  (18)Wu, Z., Ye, X., Liu, H., Zhang, H., Liu, Z., Guo, M., Li, Q., Li, J., Interactions between adsorbents and adsorbates in aqueous solutions. Pure and Applied Chemistry. 2020, 92(10), 1655-1662. 

  (19)Qian, F., Zhao, B., Guo M., Qian, Z., Wu, Z., Liu, Z., Trace doping by fluoride and sulfur to enhance adsorption capacity of manganese oxides for lithium recovery . Materials & Design, 2020, 194, 108867-108878.  

  (20)Qian, F., Zhao, B., Guo M., Qian, Z., Xu, N., Wu, Z., Liu, Z., Enhancing the Li+ adsorption and anti-dissolution properties of Li1.6Mn1.6O4 with Fe, Co doped. Hydrometallurgy, 2020, 193, 105291-105298.  

  (21)Qian, F., Zhao, B., Guo M., Li, J., Liu, Z., Wu, Z., K-Gradient Doping to Stabilize Spinel Structure of Li1.6Mn1.6O4 for Li+ Recovery [J]. Dalton Transactions, 2020, 49(31), 10939-10949.  

  (22)Zhao, B., Guo M., Qian, Z., Li, J., Wu, Z., Liu, Z., The adsorption behavior of lithium on spinel titanium oxide nanosheets with exposed (114) high-index facets [J]. Dalton Transactions, 2020, 49(40),14180-90.  

  (23)Zhao, B., Guo M., Qian, F., Qian, Z., Xu, N., Wu, Z., Liu, Z., Hydrothermal synthesis and adsorption behavior of H4Ti5O12 nanorods along [100] as lithium ion-sieves . RSC Advances, 2020, 10(58),35153-35163.  

  (24)Xu, N., Li, S., Li, W., Liu, Z., Removal of Fluoride by Graphene Oxide/Alumina Nanocomposite: Adsorbent Preparation, Characterization, Adsorption Performance and MechanismsChemistrySelect, 2020, 5, 1818-1828.  

  (25)Cao, Y., Wang. H., Ding, R., Wang, L., Liu, Z., Lv, B., Highly efficient oxidative desulfurization of dibenzothiophene using Ni modified MoO3 catalyst, Applied Catalysis A: General, 2020, 589, 117308.  

  (26)Liu, Z., Zhou, Y., Guo M., Lv, B., Wu, Z., Zhou, W., Experimental and theoretical investigations of Cs+ adsorption on crown ethers modified magnetic adsorbent, Journal of Hazardous Materials, 2019, 371, 712-720. 

  (27)    Qian, F., Guo M., Qian, Z., Li, Q., Wu, Z., Liu, Z., Highly Lithium Adsorption Capacities of H1.6Mn1.6O4 Ion-sieve by Ordered Array Structure . ChemistrySelect, 2019, 4(34):10157-10163.  

  (28)Xu, N., Li, S., Guo, M., Qian, Z., Li, W., Liu, Z., Synthesis of H4Mn5O12 Nanotubes Lithium Ion Sieve and Its Adsorption Properties for Li+ from Aqueous Solution [J]. ChemistrySelect, 2019, 4(33):9562–69. 

  (29)Sun, L., Huang, J., Liu, H., Zhang, Y., Ye, X., Zhang, H., Wu, A., Wu, Z., Adsorption of boron by CA@KH-550@EPH@NMDG (CKEN) with biomass carbonaceous aerogels as substrate. Journal of Hazardous Materials. 2018, 358, 10-19. 

  (30)Yu, X., Zhao, C., Zhang, T., Liu, Z., Molecular and dissociative O2 adsorption on the Cu2O (111) surface. Physical Chemistry Chemical Physics, 2018, 20, 20352-20362.  

  (31)Fu, L., Wang, A., Su, W., Zheng, Y., Liu, Z., A rapid electrochemical sensor fabricated using silver ions and graphene oxide. Ionics, 2018, 24, 2821-2827.  

  (32)Yu, X., Zhang, X., Meng, Y., Zhao, Y., Li, Y., Xu, W., Liu, Z., CO adsorption, dissociation and coupling formation mechanisms on Fe2C (001) surface. Applied Surface Science, 2018, 434, 464-472.  

  (33)Sun, L., Zhang, Y., Ye, X., Liu, H., Zhang, H., Wu, A., Wu, Z., Removal of I- from aqueous solutions using a biomass carbonaceous aerogel modified with KH-560. Acs Sustainable Chemistry & Engineering. 2017, 5(9), 7700-7708. 

  (34)Zhu, Y., Wang, W., Zhang, H., Ye, X., Wu, Z., Wang, A., Fast and high-capacity adsorption of Rb+ and Cs+ onto recyclable magnetic porous spheres. Chemical Engineering Journal. 2017, 327, 982-991. 

  (35)Zhu, Y., Zhang, H., Wang, W., Ye, X., Wu, Z., Wang, A., Fabrication of a magnetic porous hydrogel sphere for efficient enrichment of Rb+ and Cs+ from aqueous solution. Chemical Engineering Research & Design. 2017, 125, 214-225. 

  (36)Liu, Z., Yu, R., Dong, Y., Li, W., Lv, B., The adsorption behavior and mechanism of Cr(VI) on 3D hierarchical a-Fe2O3 structures exposed by (001) and non-(001) planes. Chemical Engineering Journal. 2017, 309, 815-823. 

  (37)Liu, Z., Yu, R., Dong, Y., Li, W., Zhou, W., Preparation of a-Fe2O3 hollow spheres, nanotubes, nanoplates and nanorings as highly efficient Cr(VI) adsorbents. RSC Adv., 2016, 6, 82854-82861. 

  (38)Xu, N., Liu* Z., Dong, Y., Hong, T., Dang, Li., Li, Wu., Controllable synthesis of mesoporous alumina with large surface area for high and fast fluoride removal, Ceramics International, 2016, 42, 15253-15260.  

  (39)Xu, N., Liu, Zhong., Bian, S., Dong, Y., Li, Wu., Preparation of MnO2–Al2O3 adsorbent with large specific surface area for fluoride removal. Particuology, 2016, 27, 66-71.  

  (40)Wang, S., Li, Q., Ye, X., Sun, Q., Wu, Z., Electrolytic preparation of Mg-La alloy in chloride molten salt: effect of electrolyte composition. Rare Metal Materials and Engineering. 2015, 44(7), 1623-1628. 

  (41)Liu, Z., Chiang, C., Li, W., Zhou, W., The role of surface hydrolysis of ferricyanide anions in crystal growth of snowflake-shaped α-Fe2O3. Chem. Comm. 2015, 51, 9350-9353. 

  (42)Yu, F.,Liu, Z., Zhou, W., Facile Synthesis of (110) Plane Exposed Au Microflowers as High Sensitive Hydrogen Peroxide Sensors”. Eur. J. Inorg. Chem., 2015, 15, 2528-2533. 

  (43)Wang, Y., Liu, Z., Li, D., Liu, Z.., Dong, Y., Li, W., Li, N., The Polymeric Nanofilm of Triazinedithiolsilane Fabricated by Self-Assembled Technique on Copper surface. Part 1: Design Strategy and Corrosion Resistance, Corrosion Science. 2015, 98, 382-390.  

  (44)Guo, T., Hu, Y., Gao, X., Ye, X., Liu, H., Wu, Z., Competitive adsorption of Li, Na, K, Rb and Cs ions onto calcium alginate-potassium tetraphenylborate composite adsorbent. Rsc Advances. 2014, 4(46), 24067-24072. 

  (45)Li, B., Liu, H., Ye, X., Li, S., Wu, Z., Rubidium and cesium ion adsorption by a potassium titanium silicate-calcium alginate composite adsorbent. Separation Science and Technology. 2014, 49(7), 1076-1085. 

  (46)Gao, X., Hu, Y., Guo, T., Ye, X., Li, Q., Guo, M., Liu, H., Wu, Z., Comparative study of the competitive adsorption of Mg, Ca and Sr ions onto resins. Adsorption Science & Technology. 2013, 31(1), 45-58. 

  (47)Hu, Y., Guo, T., Ye, X., Li, Q., Guo, M., Liu, H., Wu, Z., Dye adsorption by resins: effect of ionic strength on hydrophobic and electrostatic interactions. Chemical Engineering Journal. 2013, 228, 392-397. 

  (48)Wang, S., Li, Q., Ye, X., Sun, Q., Wu, Z., Effect of oxide and fluoride addition on electrolytic preparation of Mg-La alloy in chloride molten salt. Transactions of Nonferrous Metals Society of China. 2013, 23(10), 3104-3111. 

  (49)Liu, Z., Lv, B., Xu, Y., Wu., Hexagonal α-Fe2O3 nanorods bound by high-index facets as high-performance electrochemical sensor. J. Mater. Chem. A, 2013, 1, 3040-3046. 

  (50)Liu, Z., Lv, B., Xu, Y., Wu, D., Sun, Y., Magnetic and electrochemical behavior of rhombohedral α-Fe2O3 nanostructures with (104) dominant facets, Particuology, 2013, 11, 327-333. 

  (51)Zhang, H., Guo, T., Li, Q., Liu, H., Ye, X., Wu, Z., Iodide adsorption onto three organic-inorganic composite adsorbents. Adsorption Science & Technology. 2012, 30(5), 449-460. 

  (52)Liu, Z., Lv, B., Wu, D., Zhu, Y., Sun, Y., Precisely tailoring dendritic α-Fe2O3 structures along [10-10] directions, CrystEngComm, 2012, 14, 4074-4080.  

  (53)Liu, Z., Lv, B., Wu, D., Sun, Y., The preparation and properties of octodecahedral α-Fe2O3nanoparticles enclosed by {104} and {112} facets”, Eur. J. Inorg. Chem., 2012, 25, 4076-4081. 

  (54)Liu, Z., Lv, B., Wu, D., Sun, Y., Morphology and magnetic properties of α-Fe2O3 particles prepared by octadecylamine-assisted hydrolythermal method, Particuology, 2012, 10, 456-461.  

  (55)Zhang, H., Gao, X., Guo, T., Li, Q., Liu, H., Ye, X., Guo, M., Wu, Z., Adsorption of iodide ions on a calcium alginate-silver chloride composite adsorbent. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2011, 386(1-3), 166-171. 

  (56)Guo, M., Li, Q., Ye, X., Wu, Z., Magnesium carbonate precipitation under the influence of polyacrylamide. Powder Technology. 2010, 200(1-2), 46-51. 

  (57)Li, Q., Liu, H., Liu, T., Guo, M., Qing, B., Ye, X., Wu, Z., Strontium and calcium ion adsorption by molecularly imprinted hybrid gel. Chemical Engineering Journal. 2010, 157(2-3), 401-407. 

  (58)Guo, M., Li, Q., Liu, H., Ye, X., Qing, B., Ge, F., Wu, Z., The exploitation and utilization of magnesium resources in salt lakes. Progress in Chemistry. 2009, 21(11), 2358-2364. 

  (59)Liu, H., Qing, B., Ye, X., Li, Q., Lee, K., Wu, Z., Boron adsorption by composite magnetic particles. Chemical Engineering Journal. 2009, 151(1-3), 235-240. 

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  (62)Liu, H., You, L., Ye, X., Li, W., Wu, Z., Adsorption kinetics of an organic dye by wet hybrid gel monoliths. Journal of Sol-Gel Science and Technology. 2008, 45(3), 279-290. 

  (63)Ye, X., Liu, T., Li, Q., Liu, H., Wu, Z., Comparison of strontium and calcium adsorption onto composite magnetic particles derived from Fe3O4 and bis(trimethoxysilylpropyl)amine. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2008, 330(1), 21-27. 

  2.专利 

  (1) 一种用于液体锂资源提取的铝系吸附剂颗粒制备方法, ZL.202011340822.6, 2023.05.23. 

  (2)一种高强磷硅酸镁水泥及其制备方法, ZL.202111671118.3, 2023.03.24. 

  (3)一种锂离子筛的制备方法, ZL.201911281225.8, 2023.02.07. 

  (4棒点结构的超疏水微-纳粒子、超疏水涂层液及超疏水防腐涂层的制备方法, ZL.202110313556.6, 2022.08.23. 

  (5)一种用于液体铷铯资源提取的杂多酸盐离子筛吸附剂颗粒制备方法, ZL.202011346003.2, 2022.06.10. 

  (6)一种用于液体锂资源提取的锂离子筛吸附剂颗粒制备方法, ZL.202011346001.3, 2022.06.10. 

  (7)一种用于液体铷铯资源提取的金属铁氰化物吸附剂颗粒制备方法, ZL.202011340808.6, 2022.06.10. 

  (8)一种复合锂离子吸附柱料及其制备方法, ZL.201910456297.5, 2021.11.02. 

  (9)一种通过分截式吸附装置提取锂的方法, ZL.201811055794.6, 2021.08.24. 

  (10)一种多孔锰系锂离子筛吸附剂及其制备方法, ZL.201811494510.3, 2021.07.16. 

  (11)一种六方片状锰系锂离子筛吸附剂及其制备方法, ZL.201811495626.9, 2021.04.02. 

  (12)分截式吸脱附装置及其应用, ZL.201811056310.X, 2021.04.02. 

  (13)一种六方枝状锰系锂离子筛吸附剂及其制备方法, ZL.201811494538.7, 2021.03.16. 

  (14)一种碘离子吸附剂、其制备方法及应用, ZL.201710155686.5, 2021.03.02. 

  (15)一种导电性铝系锂离子吸附柱料及其制备方法, ZL.201910456296.0, 2021.02.26. 

  (16)磁性微孔锂吸附剂及其制备方法与应用, ZL.201811047604.6, 2021.02.23. 

  (17)一种通过磁性微孔锂吸附剂提取锂的方法, ZL.201811047676.0, 2020.06.09. 

  (18)分离硼的方法, ZL.201710743762.4, 2019.11.22. 

  (19)一种微孔铝盐锂吸附剂及其制备方法、填料和富集锂离子的方法, ZL.201610395365.8, 2019.06.18. 

  (20)铝锂中间合金的制备方法, ZL.201710034150.8, 2018.12.04. 

  (21)氯离子吸附凝胶、其应用及其吸附氯离子后的再生方法, ZL.201510677681.X, 2018.03.20. 

  (22 一种熔盐电解法制备单质金属或合金的启炉方法, ZL.201510802627.3, 2017.12.12. 

  (23)一种从酸性卤水中提取铷铯的方法, ZL.201510703793.8, 2017.12.12. 

  (24)一种离子色谱用除氯预处理柱中填充物及其制备与再生方法, ZL.201510528914.X, 2017.10.03. 

  (25)一种同时测定镁和锌含量的方法及其应用, ZL.201410077613.5, 2017.07.14. 

  (26)熔盐电解法制备镁锌中间合金的方法, ZL.201410079494.7, 2017.02.01. 

  (27)硼锶离子吸附剂、其制备及应用, ZL.201410085514.1, 2016.08.31. 

  (28)一种吸附分离系统, ZL.201410077210.0, 2016.06.22. 

  (29)凝胶球型铯离子吸附剂、其制备方法及应用, ZL.201410015386.3, 2016.01.20. 

  (30) 缓释剂及其制备方法和应用, ZL.201310574687.5, 2016.01.20. 

  (31)一种同时测定溴离子和碘离子的方法, ZL.201310557924.7, 2016.01.20. 

  (32)从混合盐溶液提取锶的方法, ZL.201410063451.X, 2015.04.15. 

  (33)凝胶球型铷/铯离子吸附剂、其制备方法及应用, ZL.201310142900.5, 2015.03.25. 

  (34)有机胺类碘离子吸附剂、其制备方法及应用, ZL.201310014484.0, 2015.02.18. 

  (35)凝胶型碘离子吸附剂、其制备方法及应用, ZL.201310014592.8, 2014.12.24. 

  (36)利用含碘卤水制备碘化银的方法, ZL.201310014822.0, 2014.09.17. 

  (37)熔盐电解产生含氯气体的吸收方法, ZL.201110140778.9, 2013.05.15. 

  (38)亚甲基蓝分光法测定阴离子表面活性物质含量的方法, ZL.200910021884.8, 2012.08.15. 

  (39)溴百里香酚蓝分光法测定阳离子表面活性物质含量的方法, ZL.200910021881.4, 2012.07.04. 

  (40)非乳化法制备过氧化镁的方法, ZL.200910117403.3, 2012.05.23. 

  (41)熔盐电解法制备镁稀土合金的方法, ZL.200910117402.9, 2011.12.21. 

  (42)双波长分光光度法测定水乳浊液中烈香杜鹃油含量的方法, ZL.200910021880.X, 2011.06.22. 

  (43)球形、放射状碳酸镁及其制备方法, ZL.200910117404.8, 2011.05.25. 

  3. 获奖荣誉 

 

    


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